Rechargeable battery

A rechargeable battery or storage battery is a group of one or more electrochemical cells. They are known as secondary cells because their electrochemical reactions are electrically reversible. Rechargeable batteries come in many different shapes and sizes, ranging anything from a button cell to megawatt systems connected to stabilize an electrical distribution network. Several different combinations of chemicals are commonly used, including: lead-acid, nickel cadmium (NiCd), nickel metal hydride (NiMH), lithium ion (Li-ion), and lithium ion polymer (Li-ion polymer).

Rechargeable batteries have lower total cost of use and environmental impact than disposable batteries. Some rechargeable battery types are available in the same sizes as disposable types. Rechargeable batteries have higher initial cost, but can be recharged very cheaply and used many times.

Contents 1 Usage and applications 2 Charging and discharging 2.1 Reverse charging 2.2 Depth of discharge 3 Active components 3.1 Table of rechargeable battery technologies 3.2 Common rechargeable battery types 3.3 Less common types 4 Developments since 2005 5 Alternatives 6 See also 7 References 8 External links

Usage and applications

Rechargeable batteries are used for automobile starters, portable consumer devices, light vehicles (such as motorized wheelchairs, golf carts, electric bicycles, and electric forklifts), tools, and uninterruptible power supplies. Emerging applications in hybrid electric vehicles and electric vehicles are driving the technology to reduce cost and weight and increase lifetime.^[1]

Normally, new rechargeable batteries have to be charged before use; newer low self-discharge batteries hold their charge for many months, and are supplied charged to about about 70% of their rated capacity.

Grid energy storage applications use rechargeable batteries for load leveling, where they store electric energy for use during peak load periods, and for renewable energy uses, such as storing power generated from photovoltaic arrays during the day to be used at night. By charging batteries during periods of low demand and returning energy to the grid during periods of high electrical demand, load-leveling helps eliminate the need for expensive peaking power plants and helps amortize the cost of generators over more hours of operation.

The US National Electrical Manufacturers Association has estimated that U.S. demand for rechargeable batteries is growing twice as fast as demand for nonrechargeables.^[2]

Charging and discharging

During charging, the positive active material is oxidized, producing electrons, and the negative material is reduced, consuming electrons. These electrons constitute the current flow in the external circuit. The electrolyte may serve as a simple buffer for ion flow between the electrodes, as in lithium-ion and nickel-cadmium cells, or it may be an active participant in the electrochemical reaction, as in lead-acid cells.

The energy used to charge rechargeable batteries usually comes from a battery charger using AC mains electricity. Chargers take from a few minutes (rapid chargers) to several hours to charge a battery. Most batteries are capable of being charged far faster than simple battery chargers are capable of; there are chargers that can charge consumer sizes of NiMH batteries in 15 minutes. Fast charges must have multiple ways of detecting full charge (voltage, temperature, etc.) to stop charging before onset of harmful overcharging.

Rechargeable multi-cell batteries are susceptible to cell damage due to reverse charging if they are fully discharged. Fully integrated battery chargers that optimize the charging current are available.

Attempting to recharge non-rechargeable batteries with unsuitable equipment may cause battery explosion.

Flow batteries, used for specialised applications, are recharged by replacing the electrolyte liquid.

Battery manufacturers' technical notes often refer to VPC; this is volts per cell, and refers to the individual secondary cells that make up the battery. For example, to charge a 12 V battery (containing 6 cells of 2 V each) at 2.3 VPC requires a voltage of 13.8 V across the battery's terminals.

Non-rechargeable alkaline and zinc-carbon cells output 1.5V when new, but this voltage gradually drops with use. Most NiMH AA and AAA batteries rate their cells at 1.2 V, and can usually be used in equipment designed to use alkaline batteries up to an end-point of 0.9 to 1.2V.

Reverse charging

Subjecting a discharged cell to a current in the direction which tends to discharge it further, rather than charge it, is called reverse charging; this damages cells. Reverse charging can occur under a number of circumstances, the three most common being:

• When a battery or cell is connected to a charging circuit the wrong way round.
• When a battery made of several cells connected in series is deeply discharged. When one cell completely discharges ahead of the rest, the live cells will apply a reverse current to the discharged cell ("cell reversal"). This significantly shortens the life of the affected cell and therefore of the battery. In some extreme cases, the reversed cell can begin to emit smoke or catch fire. If a cell is subject to voltage depression due to long-term over-charging (incorrectly called "memory effect"), it can often be repaired by deep discharge/charge cycling; but cycling a multi-cell battery into deep discharge can cause cell reversal and do more harm than good. In critical applications using Ni-Cad batteries, such as in aircraft, each cell is individually discharged by connecting a load clip across the terminals of each cell, thereby avoiding cell reversal, then charging the cells in series.

Depth of discharge

Depth of discharge (DOD) is normally stated as a percentage of the nominal ampere-hour capacity; 0% DOD means no discharge. Since the usable capacity of a battery system depends on the rate of discharge and the allowable voltage at the end of discharge, the depth of discharge must be qualified to show the way it is to be measured. Due to variations during manufacture and aging, the DOD for complete discharge can change over time or number of discharge cycles. Generally a rechargeable battery system will tolerate more charge/discharge cycles if the DOD is lower on each cycle.^[3]

Active components

The active components in a secondary cell are the chemicals that make up the positive and negative active materials, and the electrolyte. The positive and negative are made up of different materials, with the positive exhibiting a reduction potential and the negative having an oxidation potential. The sum of these potentials is the standard cell potential or voltage.

In primary cells the positive and negative electrodes are known as the cathode and anode, respectively. Although this convention is sometimes carried through to rechargeable systems — especially with lithium-ion cells, because of their origins in primary lithium cells — this practice can lead to confusion. In rechargeable cells the positive electrode is the cathode on discharge and the anode on charge, and vice versa for the negative electrode.

Table of rechargeable battery technologies

Type	Voltagea	Energy densityb			Powerc	Effi.d	E/$e	Disch.f	Cyclesg	Lifeh
	(V)	(MJ/kg)	(Wh/kg)	(Wh/L)	(W/kg)	(%)	(Wh/$)	(%/month)	(#)	(years)
Lead-acid	2.1	0.11-0.14	30-40	60-75	180	70%-92%	5-8	3%-4%	500-800	5-8 (car battery), 20 (stationary)
VRLAi	2.105
Alkaline	1.5	0.31	85	250	50	99.9%	7.7	<0.3	100-1000	<5
Ni-iron	1.2	0.18	50		100	65%	5-7.3[4]	20%-40%		50+
Ni-cadmium	1.2	0.14-0.22	40-60	50-150	150	70%-90%	1.25-2.5[4]	20%	1500
NIH2	1.5		75						20.000	15+
NiMH	1.2	0.11-0.29	30-80	140-300	250-1000	66%	2.75	30%	500-1000
Ni-zinc	1.7	0.22	60	170	900		2-3.3		100-500
Li ion	3.6	0.58	150-250	250-360	1800	80-90%	2.8-5[5]	5%-10%	1200	2-3
Li polymer	3.7	0.47-0.72	130-200	300	3000+		2.8-5.0		500~1000	2-3
LiFePO4	3.25		80-120	170 [6]	1400		0.7-3.0		2000+[7]
Li sulfur[8]	2.0	0.94-1.44[9]	400[10]	350					~100
Li titanate	2.3		90		4000+	87-95%r	0.5-1.0[11]		9000+	20+
Thin film Li	?			350	959	?	?p[12]		40000
ZnBr			75-85
V redox	1.15-1.55		25-35[13]			80%[14]		20%[14]	14,000[15]	10(stationary)[14]
NaS			150			89%-92%
Molten salt	2.58		70-110[16]	160[4]	150-220		4.54[17]		3000+	8+
Silver zinc (Ag-zinc)	1.86		130	240

Notes

For brevity, entries in the table had to be abbreviated. For a full description, please refer to the individual article about each type.

• ^a Nominal cell voltage in V.

• ^b Energy density = energy/weight or energy/size, given in three different units
• ^c Specific power = power/weight in W/kg
• ^d Charge/discharge efficiency in %
• ^e Energy/consumer price in W·h/US$ (approximately)
• ^j Safe Depth of Discharge to maintain lifecycles
• ^f Self-discharge rate in %/month
• ^g Cycle durability in number of cycles
• ^h Time durability in years
• ⁱ VRLA or recombinant includes gel batteries and absorbed glass mats
• ^p Pilot production
• ^r Depending upon charge rate

Common rechargeable battery types

Nickel-cadmium battery (NiCd)

Created by Waldemar Jungner of Sweden in 1899, based on Thomas Edison's first alkaline battery. Using nickel oxide hydroxide and metallic cadmium as electrodes. Cadmium is a toxic element, and was banned for most uses by the European Union in 2004. Nickel-cadmium batteries have been almost completely superseded by nickel-metal hydride (NiMH) batteries.

Nickel-metal hydride battery (NiMH)

First commercial types were available in 1989.^[18] These are now a common consumer and industrial type. The battery has a hydrogen-absorbing alloy for the negative electrode instead of cadmium.

Lithium-ion battery

The technology behind lithium-ion battery has not yet fully reached maturity. However, the batteries are the type of choice in many consumer electronics and have one of the best energy-to-mass ratios and a very slow loss of charge when not in use.

Lithium-ion polymer battery

These batteries are light in weight and can be made in any shape desired.

Less common types

Lithium sulfur battery

A new battery chemistry developed by Sion Power since 1994.^[19] Claims superior energy to weight than current lithium technologies on the market. Also lower material cost may help this product reach the mass market.^[20] Not to be confused with lithium sulfur dioxide (Li-SO₂) batteries which explode when recharged.

Thin film battery (TFB)

An emerging refinement of the lithium ion technology by Excellatron.^[21] The developers claim a very large increase in recharge cycles, around 40,000 cycles. Higher charge and discharge rates. At least 5C charge rate. Sustained 60C discharge, and 1000C peak discharge rate. And also a significant increase in specific energy, and energy density.^[22]

Also Infinite Power Solutions makes thin film batteries (TFB) for micro-electronic applications, that are flexible, rechargeable, solid-state lithium batteries.^[23]

Smart battery

A smart battery has the voltage monitoring circuit built inside. See also: Smart Battery System

Carbon foam-based lead acid battery

Firefly Energy has developed a carbon foam-based lead acid battery with a reported energy density of 30-40% more than their original 38 W·h/kg,^[24] with long life and very high power density.

Developments since 2005

In 2007 Yi Cui and colleagues at Stanford University's Department of Materials Science and Engineering discovered that using silicon nanowires as the anode of a lithium-ion battery increases the volumetric charge density of the anode by up to a factor of 10, the nanowire battery.^[25][26]

Another development is the paper-thin flexible self-rechargeable battery combining a thin-film organic solar cell with an extremely thin and highly flexible lithium-polymer battery, which recharges itself when exposed to light^[27].

Ceramatec, a research and development subcompany of CoorsTek, was testing a battery comprising a chunk of solid sodium metal mated to a sulfur compound by a paper-thin ceramic membrane which conducts ions back and forth to generate a current. The company claimed that it could fit about 40 kilowatt hours of energy into a package about the size of a refrigerator, and operate below 90 degrees Celsius; and that their battery would allow about 3,650 discharge/recharge cycles (or roughly 1 per day for one decade.)^[28]

Alternatives

Several alternatives to rechargeable batteries exist or are under development. For uses such as portable radios, rechargeable batteries may be replaced by clockwork mechanisms which are wound up by hand, driving dynamos, although this system may be used to charge a battery rather than to operate the radio directly. Flashlights may be driven by a dynamo directly. For transportation, uninterruptible power supply systems and laboratories, flywheel energy storage systems store energy in a spinning rotor for conversion to electric power when needed; such systems may be used to provide large pulses of power that would otherwise be objectionable on a common electrical grid. Ultracapacitors are also used; an electric screwdriver which charges in 90 seconds and will drive about half as many screws as a device using a rechargeable battery was introduced in 2007^[29], and similar flashlights have been produced.

Ultracapacitors—capacitors of extremely high value—are being developed for transportation, using a large capacitor to store energy instead of the rechargeable battery banks used in hybrid vehicles. One drawback to capacitors compared with batteries is that the terminal voltage drops rapidly; a capacitor that has 25% of its initial energy left in it will have one-half of its initial voltage. Battery systems tend to have a terminal voltage that does not decline rapidly until nearly exhausted. This characteristic complicates the design of power electronics for use with ultracapacitors. However, there are potential benefits in cycle efficiency, lifetime, and weight compared with rechargeable systems. China started using ultracapacitors on two commercial bus routes in 2006; one of them is route 11 in Shanghai.^[30]

See Battery (electricity) for comparisons between battery types.

See also

• Battery pack
• Battery recycling
• Deep cycle automotive battery manufacturers
• Fuel cell
• Mercury-containing and Rechargeable Battery Management Act
• Nickel hydrogen battery
• Power-to-weight ratio
• Rechargeable electricity storage system
• Service life
• Smart card
• Thin-film battery
• Trickle charging
• WiTricity

References

External links

• High-performance lithium battery anodes using silicon nanowires
• Scientific American - How Rechargeable Batteries Work
• Battery University – on-line resource that provides practical battery knowledge for engineers, educators, students and battery users alike.

Galvanic cells Non-rechargeable: primary cells Alkaline battery · Aluminium battery · Bunsen cell · Chromic acid cell · Clark cell · Daniell cell · Dry cell · Grove cell · Leclanché cell · Lithium battery · Mercury battery · Nickel oxyhydroxide battery · Silver-oxide battery · Weston cell · Zamboni pile · Zinc–air battery · Zinc–carbon battery · Zinc–chloride battery Rechargeable: secondary cells Lead–acid battery · Lead-acid battery (gel) · Lithium air battery · Lithium-ion battery · Lithium-ion polymer battery · Lithium iron phosphate battery · Lithium sulfur battery · Lithium-titanate battery · Nickel-cadmium battery · Nickel hydrogen battery · Nickel-iron battery · Nickel-lithium battery · Nickel-metal hydride battery · Low self-discharge NiMH battery · Nickel-zinc battery · Rechargeable alkaline battery · Sodium-sulfur battery · Vanadium redox battery · Zinc-bromine battery Kinds of cells Battery · Concentration cell · Flow battery · Fuel cell · Trough battery · Voltaic pile Parts of cells Anode · Catalyst · Cathode · Electrolyte · Half cell · Ions · Salt bridge